TY - JOUR
T1 - Dichloro(2,2,2-trichloroethoxy)vanadium(III)dietherate
T2 - synthesis and coordination chemistry
AU - Chadha, S. L.
AU - Sharma, Vijay
N1 - Funding Information:
The authors thank the CSIR, for financial help.
PY - 1987/9/15
Y1 - 1987/9/15
N2 - The compound, dichloro(2,2,2-trichloroethoxy)vanadium(III) dietherate, has been synthesized; its infrared spectrum, magnetic susceptibility and reflectance data are consistent with an alkoxy-bridged structure having an approximately octahedral geometry for vanadium(III). Its mass spectrum indicates a dimeric structure. It reacts with oxygen and nitrogen donor ligands (L) to yield complexes, VCl2(OCH2- CCl3)·2L, for which the IR spectra, magnetic susceptibility and reflectance spectra suggest a structure similar to the parent compound and the ligands are probably cis. The 1H NMR spectra of some of the compounds confirm the presence of a bridging OCH2CCl3 group.
AB - The compound, dichloro(2,2,2-trichloroethoxy)vanadium(III) dietherate, has been synthesized; its infrared spectrum, magnetic susceptibility and reflectance data are consistent with an alkoxy-bridged structure having an approximately octahedral geometry for vanadium(III). Its mass spectrum indicates a dimeric structure. It reacts with oxygen and nitrogen donor ligands (L) to yield complexes, VCl2(OCH2- CCl3)·2L, for which the IR spectra, magnetic susceptibility and reflectance spectra suggest a structure similar to the parent compound and the ligands are probably cis. The 1H NMR spectra of some of the compounds confirm the presence of a bridging OCH2CCl3 group.
UR - http://www.scopus.com/inward/record.url?scp=4243694021&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(00)81748-X
DO - 10.1016/S0020-1693(00)81748-X
M3 - Article
AN - SCOPUS:4243694021
SN - 0020-1693
VL - 132
SP - 237
EP - 240
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 2
ER -