Dicarbonyldichloridobis(trimethylphosphane)iron(II)-carbonyldichlorido- tris(trimethylphosphane)iron(II)-tetrahydrofuran (1/1/2)

Nigam P. Rath; Meghan Stouffer; Matthew K. Janssen; John R. Bleeke

doi:10.1107/S1600536811009305

Dicarbonyldichloridobis(trimethylphosphane)iron(II)-carbonyldichlorido- tris(trimethylphosphane)iron(II)-tetrahydrofuran (1/1/2)

Nigam P. Rath
, Meghan Stouffer
, Matthew K. Janssen
, John R. Bleeke

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The asymmetric unit of the title crystal, [FeCl₂(C ₃H₉P)₃(CO)]·[FeCl₂(C ₃H₉P)₂(CO)₂]·2C ₄H₈O, ontains half mol-ecules of the two closely related Fe^II complexes lying on mirror planes and a tetra-hydro-furan solvent mol-ecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both Fe^II complex mol-ecules, a distorted octa-hedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C - H⋯O inter-actions are observed in the crystal structure.

Original language	English
Pages (from-to)	m462
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	4
DOIs	https://doi.org/10.1107/S1600536811009305
State	Published - Apr 2011

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title = "Dicarbonyldichloridobis(trimethylphosphane)iron(II)-carbonyldichlorido- tris(trimethylphosphane)iron(II)-tetrahydrofuran (1/1/2)",

abstract = "The asymmetric unit of the title crystal, [FeCl2(C 3H9P)3(CO)]·[FeCl2(C 3H9P)2(CO)2]·2C 4H8O, ontains half mol-ecules of the two closely related FeII complexes lying on mirror planes and a tetra-hydro-furan solvent mol-ecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both FeII complex mol-ecules, a distorted octa-hedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C - H⋯O inter-actions are observed in the crystal structure.",

author = "Rath, \{Nigam P.\} and Meghan Stouffer and Janssen, \{Matthew K.\} and Bleeke, \{John R.\}",

year = "2011",

month = apr,

doi = "10.1107/S1600536811009305",

language = "English",

volume = "67",

pages = "m462",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "4",

}

TY - JOUR

T1 - Dicarbonyldichloridobis(trimethylphosphane)iron(II)-carbonyldichlorido- tris(trimethylphosphane)iron(II)-tetrahydrofuran (1/1/2)

AU - Rath, Nigam P.

AU - Stouffer, Meghan

AU - Janssen, Matthew K.

AU - Bleeke, John R.

PY - 2011/4

Y1 - 2011/4

N2 - The asymmetric unit of the title crystal, [FeCl2(C 3H9P)3(CO)]·[FeCl2(C 3H9P)2(CO)2]·2C 4H8O, ontains half mol-ecules of the two closely related FeII complexes lying on mirror planes and a tetra-hydro-furan solvent mol-ecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both FeII complex mol-ecules, a distorted octa-hedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C - H⋯O inter-actions are observed in the crystal structure.

AB - The asymmetric unit of the title crystal, [FeCl2(C 3H9P)3(CO)]·[FeCl2(C 3H9P)2(CO)2]·2C 4H8O, ontains half mol-ecules of the two closely related FeII complexes lying on mirror planes and a tetra-hydro-furan solvent mol-ecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both FeII complex mol-ecules, a distorted octa-hedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C - H⋯O inter-actions are observed in the crystal structure.

UR - https://www.scopus.com/pages/publications/79953787737

U2 - 10.1107/S1600536811009305

DO - 10.1107/S1600536811009305

M3 - Article

AN - SCOPUS:79953787737

SN - 1600-5368

VL - 67

SP - m462

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Dicarbonyldichloridobis(trimethylphosphane)iron(II)-carbonyldichlorido- tris(trimethylphosphane)iron(II)-tetrahydrofuran (1/1/2)

Abstract

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