Diastereoselective Michael Addition of (4′S)-Ethyl-3-(2′,2′-Dimethyl-1′,3′-dioxolan- 4′-yl) acrylate with Furyl Lithium

Dong Mei Han; Xun Tian Jiang; Jian Hong Chen; Bin Wang; Dong Lu Bai

Diastereoselective Michael Addition of (4′S)-Ethyl-3-(2′,2′-Dimethyl-1′,3′-dioxolan- 4′-yl) acrylate with Furyl Lithium

Dong Mei Han, Xun Tian Jiang, Jian Hong Chen, Bin Wang, Dong Lu Bai

Research output: Contribution to journal › Article › peer-review

Abstract

Michael addition of the chiral α,β-unsaturated ester 2 with furyl lithium proceeded in syn manner with excellent diastereoselectivity. The diastereoselectivity was not affected by the configuration of the double bond in 2.

Original language	English
Pages (from-to)	403-406
Number of pages	4
Journal	Chinese Chemical Letters
Volume	12
Issue number	5
State	Published - May 2001

Keywords

Configuration determination
Michael addition
Syn addition

Cite this

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title = "Diastereoselective Michael Addition of (4′S)-Ethyl-3-(2′,2′-Dimethyl-1′,3′-dioxolan- 4′-yl) acrylate with Furyl Lithium",

abstract = "Michael addition of the chiral α,β-unsaturated ester 2 with furyl lithium proceeded in syn manner with excellent diastereoselectivity. The diastereoselectivity was not affected by the configuration of the double bond in 2.",

keywords = "Configuration determination, Michael addition, Syn addition",

author = "Han, {Dong Mei} and Jiang, {Xun Tian} and Chen, {Jian Hong} and Bin Wang and Bai, {Dong Lu}",

year = "2001",

month = may,

language = "English",

volume = "12",

pages = "403--406",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

number = "5",

}

TY - JOUR

T1 - Diastereoselective Michael Addition of (4′S)-Ethyl-3-(2′,2′-Dimethyl-1′,3′-dioxolan- 4′-yl) acrylate with Furyl Lithium

AU - Han, Dong Mei

AU - Jiang, Xun Tian

AU - Chen, Jian Hong

AU - Wang, Bin

AU - Bai, Dong Lu

PY - 2001/5

Y1 - 2001/5

N2 - Michael addition of the chiral α,β-unsaturated ester 2 with furyl lithium proceeded in syn manner with excellent diastereoselectivity. The diastereoselectivity was not affected by the configuration of the double bond in 2.

AB - Michael addition of the chiral α,β-unsaturated ester 2 with furyl lithium proceeded in syn manner with excellent diastereoselectivity. The diastereoselectivity was not affected by the configuration of the double bond in 2.

KW - Configuration determination

KW - Michael addition

KW - Syn addition

UR - http://www.scopus.com/inward/record.url?scp=0035609222&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0035609222

SN - 1001-8417

VL - 12

SP - 403

EP - 406

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 5

ER -

Diastereoselective Michael Addition of (4′S)-Ethyl-3-(2′,2′-Dimethyl-1′,3′-dioxolan- 4′-yl) acrylate with Furyl Lithium

Abstract

Keywords

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