Detection of Secondary Amides in HCN Polymers by Dipolar Rotational Spin-Echo15N NMR

Joel R. Garbow, Jacob Schaefer, Robert Ludicky, C. N. Matthews

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The solids formed by base-catalyzed polymerization of HCN or by electrical discharge through an atmosphere of methane and ammonia have been examined by cross-polarization magic-angle spinning dipolar rotational spin-echo15N NMR. This experiment measures nitrogen-proton dipolar coupling and so can be used to count the average number of protons attached to a nitrogen whose NMR resonance is resolved. On the basis of such measurements, we conclude that the majority of the amidine or amide nitrogens in the base-catalyzed HCN polymers examined are secondary and hence peptide-like. This is not proof for the direct formation of heteropolypeptides from HCN, however, since none of the amidine or amide nitrogens observed are bonded to aliphatic carbons, as established by double cross-polarization13C and15N NMR. The anhydrous solids formed by the electrical discharge have aliphatic carbons but little or no amidine functionality, and so they too are unlikely precursors for the direct formation of heteropolypeptides.

Original languageEnglish
Pages (from-to)305-309
Number of pages5
JournalMacromolecules
Volume20
Issue number2
DOIs
StatePublished - Mar 1 1987
Externally publishedYes

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