Crystallization of quasicrystals

  • K. F. Kelton

Research output: Contribution to journalArticlepeer-review

Abstract

We present an overview of our work on the crystallization of the icosahedral phase in Al100_xMnx, Ti100-xMn, and Pd58.8U20.6Si20.6alloys and compare our results with those of others. Evidence presented suggests that the icosahedral phase in Ti60Mn37Si3 may be stable below 1100 K. The origin of arcs of diffuse scattering in TEM diffraction patterns is discussed in light of new experimental data in i-phase Ti-Mn. A model that simulates directly the i-phase transformation under isothermal and nonisothermal conditions is presented and used to analyze kinetic data for Al86Mn14alloys to obtain the first estimate for the interfacial energy between the i-phase and the crystal: σi-c= 0.03 J/m2. This is similar to the interfacial energies between crystalline metals and their liquids at the interfacial melting temperature.

Original languageEnglish
Pages (from-to)367-381
Number of pages15
JournalPhase Transitions
Volume16
Issue number1-4
DOIs
StatePublished - Jun 1 1989

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