Crystal and Molecular Structures of (l,8-Bis(2-pyridyl)-3,6-dithiaoctane)copper(I) Hexafluorophosphate and Perchlorato(l,8-bis(2-pyridyl)-3,6-dithiaoctane)copper(II) Perchlorate: Stereodynamics of the Copper(II)-Copper(I) Couple

George R. Brubaker; Joe N. Brown; Myo K. Yoo; Robert A. Kinsey; Toni M. Kutchan; Edward A. Mottel

doi:10.1021/ic50192a018

Crystal and Molecular Structures of (l,8-Bis(2-pyridyl)-3,6-dithiaoctane)copper(I) Hexafluorophosphate and Perchlorato(l,8-bis(2-pyridyl)-3,6-dithiaoctane)copper(II) Perchlorate: Stereodynamics of the Copper(II)-Copper(I) Couple

George R. Brubaker, Joe N. Brown, Myo K. Yoo, Robert A. Kinsey, Toni M. Kutchan, Edward A. Mottel

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Abstract

The crystal and molecular structures of the title compounds have been determined by single-crystal X-ray diffraction using counter data to R values of 0.061 for the copper(I) complex (1) and 0.068 for the copper(II) complex (2). The unit cell constants for 1 are a = 8.219 (1) A, b = 22.543 (3) A, and c = 11.044 (1) A; the space group is Pbcn, and Z = 4. For 2, a = 8.902 (1) A, b = 21.343 (2) A, c = 11.879 (1) A, 0 = 108.03 (1)°, the space group is P2t/c, and Z = 4. Coordination about 1 is tetrahedral and about 2 is square pyramidal.

Original language	English
Pages (from-to)	299-302
Number of pages	4
Journal	Inorganic Chemistry
Volume	18
Issue number	2
DOIs	https://doi.org/10.1021/ic50192a018
State	Published - 1979

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Brubaker, G. R., Brown, J. N., Yoo, M. K., Kinsey, R. A., Kutchan, T. M., & Mottel, E. A. (1979). Crystal and Molecular Structures of (l,8-Bis(2-pyridyl)-3,6-dithiaoctane)copper(I) Hexafluorophosphate and Perchlorato(l,8-bis(2-pyridyl)-3,6-dithiaoctane)copper(II) Perchlorate: Stereodynamics of the Copper(II)-Copper(I) Couple. Inorganic Chemistry, 18(2), 299-302. https://doi.org/10.1021/ic50192a018

@article{33f2ea6595364233b73d2b988213da67,

title = "Crystal and Molecular Structures of (l,8-Bis(2-pyridyl)-3,6-dithiaoctane)copper(I) Hexafluorophosphate and Perchlorato(l,8-bis(2-pyridyl)-3,6-dithiaoctane)copper(II) Perchlorate: Stereodynamics of the Copper(II)-Copper(I) Couple",

abstract = "The crystal and molecular structures of the title compounds have been determined by single-crystal X-ray diffraction using counter data to R values of 0.061 for the copper(I) complex (1) and 0.068 for the copper(II) complex (2). The unit cell constants for 1 are a = 8.219 (1) A, b = 22.543 (3) A, and c = 11.044 (1) A; the space group is Pbcn, and Z = 4. For 2, a = 8.902 (1) A, b = 21.343 (2) A, c = 11.879 (1) A, 0 = 108.03 (1)°, the space group is P2t/c, and Z = 4. Coordination about 1 is tetrahedral and about 2 is square pyramidal.",

author = "Brubaker, {George R.} and Brown, {Joe N.} and Yoo, {Myo K.} and Kinsey, {Robert A.} and Kutchan, {Toni M.} and Mottel, {Edward A.}",

year = "1979",

doi = "10.1021/ic50192a018",

language = "English",

volume = "18",

pages = "299--302",

journal = "Inorganic Chemistry",

issn = "0020-1669",

number = "2",

}

Brubaker, GR, Brown, JN, Yoo, MK, Kinsey, RA, Kutchan, TM & Mottel, EA 1979, 'Crystal and Molecular Structures of (l,8-Bis(2-pyridyl)-3,6-dithiaoctane)copper(I) Hexafluorophosphate and Perchlorato(l,8-bis(2-pyridyl)-3,6-dithiaoctane)copper(II) Perchlorate: Stereodynamics of the Copper(II)-Copper(I) Couple', Inorganic Chemistry, vol. 18, no. 2, pp. 299-302. https://doi.org/10.1021/ic50192a018

Crystal and Molecular Structures of (l,8-Bis(2-pyridyl)-3,6-dithiaoctane)copper(I) Hexafluorophosphate and Perchlorato(l,8-bis(2-pyridyl)-3,6-dithiaoctane)copper(II) Perchlorate: Stereodynamics of the Copper(II)-Copper(I) Couple. / Brubaker, George R.; Brown, Joe N.; Yoo, Myo K. et al.
In: Inorganic Chemistry, Vol. 18, No. 2, 1979, p. 299-302.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal and Molecular Structures of (l,8-Bis(2-pyridyl)-3,6-dithiaoctane)copper(I) Hexafluorophosphate and Perchlorato(l,8-bis(2-pyridyl)-3,6-dithiaoctane)copper(II) Perchlorate

T2 - Stereodynamics of the Copper(II)-Copper(I) Couple

AU - Brubaker, George R.

AU - Brown, Joe N.

AU - Yoo, Myo K.

AU - Kinsey, Robert A.

AU - Kutchan, Toni M.

AU - Mottel, Edward A.

PY - 1979

Y1 - 1979

N2 - The crystal and molecular structures of the title compounds have been determined by single-crystal X-ray diffraction using counter data to R values of 0.061 for the copper(I) complex (1) and 0.068 for the copper(II) complex (2). The unit cell constants for 1 are a = 8.219 (1) A, b = 22.543 (3) A, and c = 11.044 (1) A; the space group is Pbcn, and Z = 4. For 2, a = 8.902 (1) A, b = 21.343 (2) A, c = 11.879 (1) A, 0 = 108.03 (1)°, the space group is P2t/c, and Z = 4. Coordination about 1 is tetrahedral and about 2 is square pyramidal.

AB - The crystal and molecular structures of the title compounds have been determined by single-crystal X-ray diffraction using counter data to R values of 0.061 for the copper(I) complex (1) and 0.068 for the copper(II) complex (2). The unit cell constants for 1 are a = 8.219 (1) A, b = 22.543 (3) A, and c = 11.044 (1) A; the space group is Pbcn, and Z = 4. For 2, a = 8.902 (1) A, b = 21.343 (2) A, c = 11.879 (1) A, 0 = 108.03 (1)°, the space group is P2t/c, and Z = 4. Coordination about 1 is tetrahedral and about 2 is square pyramidal.

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U2 - 10.1021/ic50192a018

DO - 10.1021/ic50192a018

M3 - Article

AN - SCOPUS:0001099992

SN - 0020-1669

VL - 18

SP - 299

EP - 302

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -

Crystal and Molecular Structures of (l,8-Bis(2-pyridyl)-3,6-dithiaoctane)copper(I) Hexafluorophosphate and Perchlorato(l,8-bis(2-pyridyl)-3,6-dithiaoctane)copper(II) Perchlorate: Stereodynamics of the Copper(II)-Copper(I) Couple

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