Corrections: Chemical Ionization in Fourier Transform Mass Spectrometry: (Anal. Chem. (1981) 53(3) (428-437) (10.1021/ac00226a011))

Sahba Ghaderi, P. S. Kulkarni, Edward B. Ledford, Charles Wilkins, Michael L. Gross

Research output: Contribution to journalComment/debate

Abstract

There is an error on page 432, second paragraph. The pressure of CO was estimated to be 1 X 10−9 torr based on analysis of the methane sample using a Kratos MS-50 double focusing mass spectrometer. Calculation of Pco using the data in Figure 5, however, indicates that Pco should be about 1 × 10−7 torr. The discrepancy is probably due to the formation of CO from methane and trace amounts of water in the ion pump. The same phenomenon manifests itself for the cyclo hexanone Cl experiment discussed in the fourth paragraph, page 432. The fast consumption of CH5+ was partially due to protonation of CO. The CHO+ (unresolved from C2H5+) contributed to the m/z 29 peak intensity reported in Table IV.

Original languageEnglish
Pages (from-to)607
Number of pages1
JournalAnalytical Chemistry
Volume54
Issue number3
DOIs
StatePublished - Mar 1982

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