Contrasting picosecond photokinetics of CoII and CoIII porphyrins verify excited-state predictions

C. Drew Tait; Dewey Holten; Martin Gouterman

doi:10.1016/0009-2614(83)87290-X

Contrasting picosecond photokinetics of Co^II and Co^III porphyrins verify excited-state predictions

C. Drew Tait
, Dewey Holten
, Martin Gouterman

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

Using picosecond transient absorption techniques, we have different low-lying excited states for several Co^II and Co^III porphyrins. These differences are interpreted in terms of theoretical calculations that predict the lowest-energy excited states to be ²(π·d) in Co^II and ³(d, d) in Co^III.

Original language	English
Pages (from-to)	268-272
Number of pages	5
Journal	Chemical Physics Letters
Volume	100
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(83)87290-X
State	Published - Sep 9 1983

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@article{28cbfee194e14ad6b82526aacd4b7f30,

title = "Contrasting picosecond photokinetics of CoII and CoIII porphyrins verify excited-state predictions",

abstract = "Using picosecond transient absorption techniques, we have different low-lying excited states for several CoII and CoIII porphyrins. These differences are interpreted in terms of theoretical calculations that predict the lowest-energy excited states to be 2(π·d) in CoII and 3(d, d) in CoIII.",

author = "Tait, \{C. Drew\} and Dewey Holten and Martin Gouterman",

year = "1983",

month = sep,

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doi = "10.1016/0009-2614(83)87290-X",

language = "English",

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journal = "Chemical Physics Letters",

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TY - JOUR

T1 - Contrasting picosecond photokinetics of CoII and CoIII porphyrins verify excited-state predictions

AU - Tait, C. Drew

AU - Holten, Dewey

AU - Gouterman, Martin

PY - 1983/9/9

Y1 - 1983/9/9

N2 - Using picosecond transient absorption techniques, we have different low-lying excited states for several CoII and CoIII porphyrins. These differences are interpreted in terms of theoretical calculations that predict the lowest-energy excited states to be 2(π·d) in CoII and 3(d, d) in CoIII.

AB - Using picosecond transient absorption techniques, we have different low-lying excited states for several CoII and CoIII porphyrins. These differences are interpreted in terms of theoretical calculations that predict the lowest-energy excited states to be 2(π·d) in CoII and 3(d, d) in CoIII.

UR - https://www.scopus.com/pages/publications/0004200937

U2 - 10.1016/0009-2614(83)87290-X

DO - 10.1016/0009-2614(83)87290-X

M3 - Article

AN - SCOPUS:0004200937

SN - 0009-2614

VL - 100

SP - 268

EP - 272

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3

ER -

Contrasting picosecond photokinetics of Co^II and Co^III porphyrins verify excited-state predictions

Abstract

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