Chlorosulphuric acid as a non-aqueous solvent-X Conductometric and spectral studies of some uranium (IV) and (VI) compounds in chlorosulphuric acid

R. C. Paul; D. Konwer; D. S. Dhillon; Vijay Sharma; J. K. Puri

doi:10.1016/0022-1902(79)80273-0

Chlorosulphuric acid as a non-aqueous solvent-X Conductometric and spectral studies of some uranium (IV) and (VI) compounds in chlorosulphuric acid

R. C. Paul
, D. Konwer
, D. S. Dhillon
, Vijay Sharma
, J. K. Puri

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Uranium(VI) oxide, and uranyl sulphate, chloride, oxalate, formate and acetate solvolyse to give UO₂(SO₃Cl)₂ in HSO₃Cl. Uranium(VI) chloride forms H[U(SO₃Cl)₇] or H₂[U(SO₃Cl)₈] which behave as non-electrolytes in HSO₃Cl. Uranium(IV) acetate forms H₂[U(SO₃Cl)₆] and behave as a very weak acid in HSO₃Cl.

Original language	English
Pages (from-to)	825-826
Number of pages	2
Journal	Journal of Inorganic and Nuclear Chemistry
Volume	41
Issue number	6
DOIs	https://doi.org/10.1016/0022-1902(79)80273-0
State	Published - 1979

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title = "Chlorosulphuric acid as a non-aqueous solvent-X Conductometric and spectral studies of some uranium (IV) and (VI) compounds in chlorosulphuric acid",

abstract = "Uranium(VI) oxide, and uranyl sulphate, chloride, oxalate, formate and acetate solvolyse to give UO2(SO3Cl)2 in HSO3Cl. Uranium(VI) chloride forms H[U(SO3Cl)7] or H2[U(SO3Cl)8] which behave as non-electrolytes in HSO3Cl. Uranium(IV) acetate forms H2[U(SO3Cl)6] and behave as a very weak acid in HSO3Cl.",

author = "Paul, \{R. C.\} and D. Konwer and Dhillon, \{D. S.\} and Vijay Sharma and Puri, \{J. K.\}",

year = "1979",

doi = "10.1016/0022-1902(79)80273-0",

language = "English",

volume = "41",

pages = "825--826",

journal = "Journal of Inorganic and Nuclear Chemistry",

issn = "0022-1902",

number = "6",

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TY - JOUR

T1 - Chlorosulphuric acid as a non-aqueous solvent-X Conductometric and spectral studies of some uranium (IV) and (VI) compounds in chlorosulphuric acid

AU - Paul, R. C.

AU - Konwer, D.

AU - Dhillon, D. S.

AU - Sharma, Vijay

AU - Puri, J. K.

PY - 1979

Y1 - 1979

N2 - Uranium(VI) oxide, and uranyl sulphate, chloride, oxalate, formate and acetate solvolyse to give UO2(SO3Cl)2 in HSO3Cl. Uranium(VI) chloride forms H[U(SO3Cl)7] or H2[U(SO3Cl)8] which behave as non-electrolytes in HSO3Cl. Uranium(IV) acetate forms H2[U(SO3Cl)6] and behave as a very weak acid in HSO3Cl.

AB - Uranium(VI) oxide, and uranyl sulphate, chloride, oxalate, formate and acetate solvolyse to give UO2(SO3Cl)2 in HSO3Cl. Uranium(VI) chloride forms H[U(SO3Cl)7] or H2[U(SO3Cl)8] which behave as non-electrolytes in HSO3Cl. Uranium(IV) acetate forms H2[U(SO3Cl)6] and behave as a very weak acid in HSO3Cl.

UR - https://www.scopus.com/pages/publications/49249149729

U2 - 10.1016/0022-1902(79)80273-0

DO - 10.1016/0022-1902(79)80273-0

M3 - Article

AN - SCOPUS:49249149729

SN - 0022-1902

VL - 41

SP - 825

EP - 826

JO - Journal of Inorganic and Nuclear Chemistry

JF - Journal of Inorganic and Nuclear Chemistry

IS - 6

ER -

Chlorosulphuric acid as a non-aqueous solvent-X Conductometric and spectral studies of some uranium (IV) and (VI) compounds in chlorosulphuric acid

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