TY - JOUR
T1 - Chlorobis(2-chloroe thoxy)vanadium(III) and chlorobis(2,2,2-trichloroethoxy)vanadium(III)diethyl ether solvate
T2 - Synthesis and coordination chemistry
AU - Chadha, S. L.
AU - Sharma, Vijay
AU - Uppal, Kamini
N1 - Funding Information:
Research, New Delhi (India) for financial help.,
PY - 1987/4/1
Y1 - 1987/4/1
N2 - The compounds VC1(OCH2CH2Cl)2 and VC1(OCH2CCl3)2.2Et2O have been synthesised. They form complexes VCl(OR)2.2L (R=R'=CH2CH2C1 & R = R″=CH2CC13) with monodentate oxygen or nitrogen donor ligands(L) for which the magnetic moments indicate antiferromagnetic interactions The electronic spectra for the complexes are consistent with approximately octahedral coordination of V(III) involving chloride, alkoxy and two ligands. The IR bands⋎C-O) of the complexes are consistent with alkoxy bridged dimeric structures in which the ligands (L) are probably cis.
AB - The compounds VC1(OCH2CH2Cl)2 and VC1(OCH2CCl3)2.2Et2O have been synthesised. They form complexes VCl(OR)2.2L (R=R'=CH2CH2C1 & R = R″=CH2CC13) with monodentate oxygen or nitrogen donor ligands(L) for which the magnetic moments indicate antiferromagnetic interactions The electronic spectra for the complexes are consistent with approximately octahedral coordination of V(III) involving chloride, alkoxy and two ligands. The IR bands⋎C-O) of the complexes are consistent with alkoxy bridged dimeric structures in which the ligands (L) are probably cis.
UR - http://www.scopus.com/inward/record.url?scp=84946282097&partnerID=8YFLogxK
U2 - 10.1080/00945718708059449
DO - 10.1080/00945718708059449
M3 - Article
AN - SCOPUS:84946282097
SN - 0094-5714
VL - 17
SP - 409
EP - 418
JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
IS - 4
ER -