Chemoselective Transfer Hydrogenation of Nitroarenes Catalyzed by Highly Dispersed, Supported Nickel Nanoparticles

Chengjun Jiang; Zeyu Shang; Xinhua Liang

doi:10.1021/acscatal.5b00969

Chemoselective Transfer Hydrogenation of Nitroarenes Catalyzed by Highly Dispersed, Supported Nickel Nanoparticles

Chengjun Jiang
, Zeyu Shang
, Xinhua Liang

Department of Energy, Environmental & Chemical Engineering

Research output: Contribution to journal › Article › peer-review

149 Scopus citations

Abstract

A recyclable highly dispersed Ni/SiO₂ catalyst was prepared by atomic layer deposition. Chemoselective reduction of nitroarenes was studied using the prepared Ni/SiO₂ as the catalyst and hydrazine hydrate as a hydrogen donor. Different kinds of nitroarenes were converted to the corresponding anilines with high yields. The high activity of the catalysts could be a result of the highly dispersed Ni nanoparticles. (Chemical Presented).

Original language	English
Pages (from-to)	4814-4818
Number of pages	5
Journal	ACS Catalysis
Volume	5
Issue number	8
DOIs	https://doi.org/10.1021/acscatal.5b00969
State	Published - Aug 7 2015

Keywords

atomic layer deposition (ALD)
chemoselective
heterogeneous catalysis
nickel nanoparticles
nitroarenes
transfer hydrogenation

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10.1021/acscatal.5b00969

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title = "Chemoselective Transfer Hydrogenation of Nitroarenes Catalyzed by Highly Dispersed, Supported Nickel Nanoparticles",

abstract = "A recyclable highly dispersed Ni/SiO2 catalyst was prepared by atomic layer deposition. Chemoselective reduction of nitroarenes was studied using the prepared Ni/SiO2 as the catalyst and hydrazine hydrate as a hydrogen donor. Different kinds of nitroarenes were converted to the corresponding anilines with high yields. The high activity of the catalysts could be a result of the highly dispersed Ni nanoparticles. (Chemical Presented).",

keywords = "atomic layer deposition (ALD), chemoselective, heterogeneous catalysis, nickel nanoparticles, nitroarenes, transfer hydrogenation",

author = "Chengjun Jiang and Zeyu Shang and Xinhua Liang",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = aug,

day = "7",

doi = "10.1021/acscatal.5b00969",

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journal = "ACS Catalysis",

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T1 - Chemoselective Transfer Hydrogenation of Nitroarenes Catalyzed by Highly Dispersed, Supported Nickel Nanoparticles

AU - Jiang, Chengjun

AU - Shang, Zeyu

AU - Liang, Xinhua

PY - 2015/8/7

Y1 - 2015/8/7

N2 - A recyclable highly dispersed Ni/SiO2 catalyst was prepared by atomic layer deposition. Chemoselective reduction of nitroarenes was studied using the prepared Ni/SiO2 as the catalyst and hydrazine hydrate as a hydrogen donor. Different kinds of nitroarenes were converted to the corresponding anilines with high yields. The high activity of the catalysts could be a result of the highly dispersed Ni nanoparticles. (Chemical Presented).

AB - A recyclable highly dispersed Ni/SiO2 catalyst was prepared by atomic layer deposition. Chemoselective reduction of nitroarenes was studied using the prepared Ni/SiO2 as the catalyst and hydrazine hydrate as a hydrogen donor. Different kinds of nitroarenes were converted to the corresponding anilines with high yields. The high activity of the catalysts could be a result of the highly dispersed Ni nanoparticles. (Chemical Presented).

KW - atomic layer deposition (ALD)

KW - chemoselective

KW - heterogeneous catalysis

KW - nickel nanoparticles

KW - nitroarenes

KW - transfer hydrogenation

UR - https://www.scopus.com/pages/publications/84938703784

U2 - 10.1021/acscatal.5b00969

DO - 10.1021/acscatal.5b00969

M3 - Article

AN - SCOPUS:84938703784

SN - 2155-5435

VL - 5

SP - 4814

EP - 4818

JO - ACS Catalysis

JF - ACS Catalysis

IS - 8

ER -

Chemoselective Transfer Hydrogenation of Nitroarenes Catalyzed by Highly Dispersed, Supported Nickel Nanoparticles

Abstract

Keywords

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