CD additivity in trichothecene benzoates: application as a microanalytical method for trichothecene characterization

Eugene M. Oltz, Koji Nakanishi, Boris Yagen, David G. Corley, George E. Rottinghaus, Michael S. Tempesta

Research output: Contribution to journalArticle

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Abstract

The additivity relation in A values of split CD curves previously established with pyranose p-bromobenzoates was shown to be valid for p-bromobenzoates of the cage-like trichothecene system (which also possesses a primary hydroxyl group). This suggests that additivity is generally valid even for congested multichromophoric molecules. The relation has been integrated Into a new micro method for trichothecene characterization, which was applied to a new trichothecene from Fusarium sporotrichioides (MC-72083) at a sub- μg level.

Original languageEnglish
Pages (from-to)2615-2624
Number of pages10
JournalTetrahedron
Volume42
Issue number10
DOIs
StatePublished - 1986

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    Oltz, E. M., Nakanishi, K., Yagen, B., Corley, D. G., Rottinghaus, G. E., & Tempesta, M. S. (1986). CD additivity in trichothecene benzoates: application as a microanalytical method for trichothecene characterization. Tetrahedron, 42(10), 2615-2624. https://doi.org/10.1016/S0040-4020(01)90546-0