TY - JOUR
T1 - Cationic Alkynyl Heck Reaction toward Substituted Allenes Using BobCat
T2 - A New Hybrid Pd(0)-Catalyst Incorporating a Water-Soluble dba Ligand
AU - Neff, Robynne K.
AU - Frantz, Doug E.
N1 - Publisher Copyright:
© 2018 American Chemical Society.
PY - 2018/12/19
Y1 - 2018/12/19
N2 - The cationic alkynyl Heck reaction between aryl triflates and alkynes to give substituted allenes is described. Key to the success of this method was the discovery and development of a new hybrid Pd(0)-catalyst, BobCat, that incorporates a water-soluble dba-ligand and biaryl phosphine ligand to provide substituted allenes in good yields under mild reaction conditions.
AB - The cationic alkynyl Heck reaction between aryl triflates and alkynes to give substituted allenes is described. Key to the success of this method was the discovery and development of a new hybrid Pd(0)-catalyst, BobCat, that incorporates a water-soluble dba-ligand and biaryl phosphine ligand to provide substituted allenes in good yields under mild reaction conditions.
UR - http://www.scopus.com/inward/record.url?scp=85058551532&partnerID=8YFLogxK
U2 - 10.1021/jacs.8b11759
DO - 10.1021/jacs.8b11759
M3 - Article
C2 - 30521312
AN - SCOPUS:85058551532
SN - 0002-7863
VL - 140
SP - 17428
EP - 17432
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 50
ER -