TY - JOUR
T1 - Carbenes in Constrained Systems I
T2 - 1,3 CH, Insertion Reaction of Adamantylidene within the β‐Cyclodextrin Cavity
AU - Brinker, Udo H.
AU - Buchkremer, Rüdiger
AU - Kolodziejczyk, Margaret
AU - Kupfer, René
AU - Rosenberg, Murray
AU - Poliks, Mark D.
AU - Orlando, Mario
AU - Gross, Michael L.
PY - 1993/9
Y1 - 1993/9
N2 - The first intra‐ and intermolecular carbene insertions within any constrained molecular reaction vessel was detected in the photolysis of the solid inclusion complex 1·β‐cyclodextrin(CD). NMR and/or FAB mass spectra reveal the formation of products such as 2·β‐CD and 3·β‐CD. (Figure Presented.)
AB - The first intra‐ and intermolecular carbene insertions within any constrained molecular reaction vessel was detected in the photolysis of the solid inclusion complex 1·β‐cyclodextrin(CD). NMR and/or FAB mass spectra reveal the formation of products such as 2·β‐CD and 3·β‐CD. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33750552918&partnerID=8YFLogxK
U2 - 10.1002/anie.199313441
DO - 10.1002/anie.199313441
M3 - Article
AN - SCOPUS:33750552918
SN - 0570-0833
VL - 32
SP - 1344
EP - 1345
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 9
ER -