TY - JOUR
T1 - Calixarenes as hosts in aqueous media
T2 - Inclusion complexation of ferrocene derivatives by a water-soluble calix[6]arene
AU - Zhang, Litao
AU - MacÍas, Alba
AU - Lu, Tianbao
AU - Gordon, Jeffrey I.
AU - Gokel, George W.
AU - Kaifer, Angel E.
PY - 1993
Y1 - 1993
N2 - The complexation of trimethyl(ferrocenylmethyl)ammonium hexafluorophosphate 1·(BF6), heptyldimethyl(ferrocenylmethyl)ammonium bromide 2·(Br) and ferrocenylmethanol 3 by a sulfonated calix[6]arene host was investigated in aqueous media using electrochemical and 1H NMR spectroscopic techniques; the binding interactions between the calixarene host and the surveyed guests are similar to those operating in the complexation of organic compounds by cyclodextrin or cyclophane hosts in aqueous media.
AB - The complexation of trimethyl(ferrocenylmethyl)ammonium hexafluorophosphate 1·(BF6), heptyldimethyl(ferrocenylmethyl)ammonium bromide 2·(Br) and ferrocenylmethanol 3 by a sulfonated calix[6]arene host was investigated in aqueous media using electrochemical and 1H NMR spectroscopic techniques; the binding interactions between the calixarene host and the surveyed guests are similar to those operating in the complexation of organic compounds by cyclodextrin or cyclophane hosts in aqueous media.
UR - http://www.scopus.com/inward/record.url?scp=37049072479&partnerID=8YFLogxK
U2 - 10.1039/C39930001017
DO - 10.1039/C39930001017
M3 - Article
AN - SCOPUS:37049072479
SN - 0022-4936
SP - 1017
EP - 1019
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 12
ER -