C-H bond activation via concerted metalation-deprotonation at a palladium(iii) center

Keyphrases

• Palladium 100%
• C-H Bond Activation 100%
• Concerted Metalation-deprotonation 100%
• Rate Limiting 66%
• C-H Activation 66%
• Hydrogen Bonds (H-bonds) 33%
• Dimethyl 33%
• Acetate 33%
• Effect Study 33%
• Hexafluorophosphate 33%
• Density Functional Calculations 33%
• Ligand Structure 33%
• Flexible Ligand 33%
• Kinetic Isotope Effect 33%
• UV-VIS Spectroscopy 33%
• Pyridinophane 33%
• Bond Activation 33%
• Mild Oxidant 33%
• Ligand Coordination 33%
• Cyclometalated 33%
• Agostic Interactions 33%
• Metalacycles 33%
• Ligand Rearrangement 33%
• Ferrocenium 33%

Chemistry

• Palladium 100%
• Metalation 100%
• C-H Bond Activation 100%
• Deprotonation 100%
• Dyphylline 100%
• Spectroscopy 25%
• EPR Spectroscopy 25%
• Kinetic Isotope Effect 25%
• UV/VIS Spectroscopy 25%
• Density Functional Theory 25%
• Ligand Structure 25%