Arene transition metal chemistry. III. Arene exchange phenomena

E. L. Muetterties; John R. Bleeke; Allen C. Sievert

doi:10.1016/S0022-328X(00)87871-7

Arene transition metal chemistry. III. Arene exchange phenomena

E. L. Muetterties, John R. Bleeke, Allen C. Sievert

Department of Chemistry

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141 Scopus citations

Abstract

Arene exchange between free arene and an arene-transition metal complex is reviewed with respect to structure, thermodynamics, kinetics and reaction mechanism. Catalysis of such arene exchange is also examined. Experimental results are presented for arene exchange between arene and the arene-metal complexes: η⁶-arene-1,5-cyclooctadieneruthenium, the cationic η⁶-arene-1,5-cyclooctadieneiridium and η⁶-arenetricarbonylmolybdenum. Mechanistic features of these exchange reactions are discussed.

Original language	English
Pages (from-to)	197-216
Number of pages	20
Journal	Journal of Organometallic Chemistry
Volume	178
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)87871-7
State	Published - Sep 25 1979

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Arene transition metal chemistry. III. Arene exchange phenomena

Abstract

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