Anhydride-functionalized fullerene: a versatile precursor for fullerene-based materials

Gyu Seong Heo; Bongjin Moon

doi:10.1016/j.tetlet.2008.07.064

Anhydride-functionalized fullerene: a versatile precursor for fullerene-based materials

Gyu Seong Heo, Bongjin Moon

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Soluble phthalic anhydride-functionalized fullerene was generated via simple pyrolysis of the corresponding di-t-butyl phthalate precursor at 200 °C for 120 min. This non-chemical method for generating electrophilic fullerene may be advantageous for the preparation of various fullerene-containing materials. The utility of the resulting fullerene anhydride was demonstrated by solution coupling reaction with PEG-amine, surface reaction with amine-functionalized glass, and hydrolysis reaction to form amphiphilic fullerene.

Original language	English
Pages (from-to)	5540-5543
Number of pages	4
Journal	Tetrahedron Letters
Volume	49
Issue number	38
DOIs	https://doi.org/10.1016/j.tetlet.2008.07.064
State	Published - Sep 15 2008

Keywords

Anhydrides
Fullerenes
Phthalates
Pyrolysis

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10.1016/j.tetlet.2008.07.064

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title = "Anhydride-functionalized fullerene: a versatile precursor for fullerene-based materials",

abstract = "Soluble phthalic anhydride-functionalized fullerene was generated via simple pyrolysis of the corresponding di-t-butyl phthalate precursor at 200 °C for 120 min. This non-chemical method for generating electrophilic fullerene may be advantageous for the preparation of various fullerene-containing materials. The utility of the resulting fullerene anhydride was demonstrated by solution coupling reaction with PEG-amine, surface reaction with amine-functionalized glass, and hydrolysis reaction to form amphiphilic fullerene.",

keywords = "Anhydrides, Fullerenes, Phthalates, Pyrolysis",

author = "Heo, {Gyu Seong} and Bongjin Moon",

note = "Funding Information: This work was supported by the Korea Research Foundation under grant KRF-2006-005-J02101 and by the Center for Bioactive Molecular Hybrid (CBMH) of KOSEF. G.S.H. gratefully acknowledges a fellowship of the BK21 program from the Ministry of Education and Human Resources Development. ",

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T2 - a versatile precursor for fullerene-based materials

AU - Heo, Gyu Seong

AU - Moon, Bongjin

N1 - Funding Information: This work was supported by the Korea Research Foundation under grant KRF-2006-005-J02101 and by the Center for Bioactive Molecular Hybrid (CBMH) of KOSEF. G.S.H. gratefully acknowledges a fellowship of the BK21 program from the Ministry of Education and Human Resources Development.

PY - 2008/9/15

Y1 - 2008/9/15

N2 - Soluble phthalic anhydride-functionalized fullerene was generated via simple pyrolysis of the corresponding di-t-butyl phthalate precursor at 200 °C for 120 min. This non-chemical method for generating electrophilic fullerene may be advantageous for the preparation of various fullerene-containing materials. The utility of the resulting fullerene anhydride was demonstrated by solution coupling reaction with PEG-amine, surface reaction with amine-functionalized glass, and hydrolysis reaction to form amphiphilic fullerene.

AB - Soluble phthalic anhydride-functionalized fullerene was generated via simple pyrolysis of the corresponding di-t-butyl phthalate precursor at 200 °C for 120 min. This non-chemical method for generating electrophilic fullerene may be advantageous for the preparation of various fullerene-containing materials. The utility of the resulting fullerene anhydride was demonstrated by solution coupling reaction with PEG-amine, surface reaction with amine-functionalized glass, and hydrolysis reaction to form amphiphilic fullerene.

KW - Anhydrides

KW - Fullerenes

KW - Phthalates

KW - Pyrolysis

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DO - 10.1016/j.tetlet.2008.07.064

M3 - Article

AN - SCOPUS:48549084017

SN - 0040-4039

VL - 49

SP - 5540

EP - 5543

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 38

ER -

Anhydride-functionalized fullerene: a versatile precursor for fullerene-based materials

Abstract

Keywords

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