Analysis of Anionic Surfactants by Mass Spectrometry/Mass Spectrometry with Fast Atom Bombardment

Philip A. Lyon; William L. Stebbings; Frank W. Crow; Kenneth B. Tomer; Dixie L. Lippstreu; Michael L. Gross

doi:10.1021/ac00265a004

Analysis of Anionic Surfactants by Mass Spectrometry/Mass Spectrometry with Fast Atom Bombardment

Philip A. Lyon, William L. Stebbings, Frank W. Crow, Kenneth B. Tomer, Dixie L. Lippstreu, Michael L. Gross

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Abstract

Fast atom bombardment (FAB) In conjunction with mass spectrometry/mass spectrometry (MS/MS) was applied to the analysis of anionic sufactants for the first time. Pure materials and commercial products were Investigated. Molecular weight distributions of commercial surfactants could be obtained from either the positive or negative FAB spectra. Collisionally activated dissociation (CAD) spectra of selected Ions were used to confirm strutural Identification. Classes successfully characterized Include alkyl and alkylaryl sulfates and sulfonates, alcohol ether sulfates, α-olefln sulfonates, fatty acid salts, sulfosuccinate diesters, and N-acylated amino acids. The FAB MS/MS technique permits the rapid analysis of these Ionic surfactants without any derlvatization or preseparation.

Original language	English
Pages (from-to)	8-13
Number of pages	6
Journal	Analytical Chemistry
Volume	56
Issue number	1
DOIs	https://doi.org/10.1021/ac00265a004
State	Published - Jan 1984

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abstract = "Fast atom bombardment (FAB) In conjunction with mass spectrometry/mass spectrometry (MS/MS) was applied to the analysis of anionic sufactants for the first time. Pure materials and commercial products were Investigated. Molecular weight distributions of commercial surfactants could be obtained from either the positive or negative FAB spectra. Collisionally activated dissociation (CAD) spectra of selected Ions were used to confirm strutural Identification. Classes successfully characterized Include alkyl and alkylaryl sulfates and sulfonates, alcohol ether sulfates, α-olefln sulfonates, fatty acid salts, sulfosuccinate diesters, and N-acylated amino acids. The FAB MS/MS technique permits the rapid analysis of these Ionic surfactants without any derlvatization or preseparation.",

author = "Lyon, {Philip A.} and Stebbings, {William L.} and Crow, {Frank W.} and Tomer, {Kenneth B.} and Lippstreu, {Dixie L.} and Gross, {Michael L.}",

year = "1984",

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T1 - Analysis of Anionic Surfactants by Mass Spectrometry/Mass Spectrometry with Fast Atom Bombardment

AU - Lyon, Philip A.

AU - Stebbings, William L.

AU - Crow, Frank W.

AU - Tomer, Kenneth B.

AU - Lippstreu, Dixie L.

AU - Gross, Michael L.

PY - 1984/1

Y1 - 1984/1

N2 - Fast atom bombardment (FAB) In conjunction with mass spectrometry/mass spectrometry (MS/MS) was applied to the analysis of anionic sufactants for the first time. Pure materials and commercial products were Investigated. Molecular weight distributions of commercial surfactants could be obtained from either the positive or negative FAB spectra. Collisionally activated dissociation (CAD) spectra of selected Ions were used to confirm strutural Identification. Classes successfully characterized Include alkyl and alkylaryl sulfates and sulfonates, alcohol ether sulfates, α-olefln sulfonates, fatty acid salts, sulfosuccinate diesters, and N-acylated amino acids. The FAB MS/MS technique permits the rapid analysis of these Ionic surfactants without any derlvatization or preseparation.

AB - Fast atom bombardment (FAB) In conjunction with mass spectrometry/mass spectrometry (MS/MS) was applied to the analysis of anionic sufactants for the first time. Pure materials and commercial products were Investigated. Molecular weight distributions of commercial surfactants could be obtained from either the positive or negative FAB spectra. Collisionally activated dissociation (CAD) spectra of selected Ions were used to confirm strutural Identification. Classes successfully characterized Include alkyl and alkylaryl sulfates and sulfonates, alcohol ether sulfates, α-olefln sulfonates, fatty acid salts, sulfosuccinate diesters, and N-acylated amino acids. The FAB MS/MS technique permits the rapid analysis of these Ionic surfactants without any derlvatization or preseparation.

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Analysis of Anionic Surfactants by Mass Spectrometry/Mass Spectrometry with Fast Atom Bombardment

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