Ammonia recovery from simulated anaerobic digestate using a two-stage direct contact membrane distillation process

Ammonia is a key inorganic contaminant in wastewater and an important nutrient element for agriculture. Herein, a two-stage direct contact membrane distillation (DCMD) system was developed and investigated for ammonia recovery from a synthetic anaerobic digestate. In the 1st stage DCMD (DCMD-1), both ammonia and water moved across MD membrane to realize ammonia separation, while in the 2nd stage (DCMD-2), only water migrated and as a result ammonia was concentrated. It was found that increasing the initial feed solution pH could enhance ammonia removal in the DCMD-1 from 16.0 ± 2.0% (no pH adjustment) to 84.2 ± 1.9% (pH 12). A higher feed solution temperature increased both ammonia flux and water flux. The optimal condition was determined as an initial feed pH of 12, a feed temperature of 60°C, and the 0.6 M H₂SO₄ adsorption solution. With the addition of the DCMD-2, the ammonia concentration was improved from 3 g L⁻¹ to 7.8 ± 0.2 g L⁻¹, which was further enhanced to 26.3 ± 3.0 g L⁻¹ after five batches of operation. These results have demonstrated the feasibility of a two-stage DCMD system for ammonia recovery from anaerobic digestate and warrant further investigation of several key issues that may advance this technology. Practitioner points: A two-stage membrane distillation system is developed to remove and recover ammonia from anaerobic digester effluents. The system uses ammonia/ammonium equilibrium to separate ammonia in the 1st stage and then concentrate it in the 2nd stage. A high initial pH of the feed solution plays a key role in achieving high ammonia removal. Minimizing the volume of permeate solution can increase the ammonia concentration.