Acylation Reactions of Phenylhydrazines. Preparation and Properties of New Diacylphenylhydrazines

Michael J. Hearn; Debra J. Magee; Randl Alhart; Marye Gleva; Susan Goldstein; Flona Levy; Colette Muenzen; Isabel Neuringer; Mary Racln; Judlth Rosenberg; Holly Silva; Paula Williams

doi:10.1021/je00039a036

Acylation Reactions of Phenylhydrazines. Preparation and Properties of New Diacylphenylhydrazines

Michael J. Hearn, Debra J. Magee, Randl Alhart, Marye Gleva, Susan Goldstein, Flona Levy, Colette Muenzen, Isabel Neuringer, Mary Racln, Judlth Rosenberg, Holly Silva, Paula Williams

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6 Scopus citations

Abstract

Anhydride acylation reactions of a variety of substituted arylhydrazines under mild conditions led to controlled formation of the acid phenylhydrazides I (Table I). The procedures were tailored to the particular state of the starting arylhydrazine. Second-stage acylation of phenylhydrazides conveniently produced the N,N'-diacylphenylhydrazines II (Table II), In which the acyl groups were the same or nonidentical. β acylation of phenylhydrazine resulted In significant changes In the ultraviolet spectrum (Table III); the ultraviolet spectra thus provide useful data in the determination of the extent and site of acylation.

Original language	English
Pages (from-to)	129-131
Number of pages	3
Journal	Journal of Chemical and Engineering Data
Volume	30
Issue number	1
DOIs	https://doi.org/10.1021/je00039a036
State	Published - 1985

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title = "Acylation Reactions of Phenylhydrazines. Preparation and Properties of New Diacylphenylhydrazines",

abstract = "Anhydride acylation reactions of a variety of substituted arylhydrazines under mild conditions led to controlled formation of the acid phenylhydrazides I (Table I). The procedures were tailored to the particular state of the starting arylhydrazine. Second-stage acylation of phenylhydrazides conveniently produced the N,N'-diacylphenylhydrazines II (Table II), In which the acyl groups were the same or nonidentical. β acylation of phenylhydrazine resulted In significant changes In the ultraviolet spectrum (Table III); the ultraviolet spectra thus provide useful data in the determination of the extent and site of acylation.",

author = "Hearn, {Michael J.} and Magee, {Debra J.} and Randl Alhart and Marye Gleva and Susan Goldstein and Flona Levy and Colette Muenzen and Isabel Neuringer and Mary Racln and Judlth Rosenberg and Holly Silva and Paula Williams",

year = "1985",

doi = "10.1021/je00039a036",

language = "English",

volume = "30",

pages = "129--131",

journal = "Journal of Chemical and Engineering Data",

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TY - JOUR

T1 - Acylation Reactions of Phenylhydrazines. Preparation and Properties of New Diacylphenylhydrazines

AU - Hearn, Michael J.

AU - Magee, Debra J.

AU - Alhart, Randl

AU - Gleva, Marye

AU - Goldstein, Susan

AU - Levy, Flona

AU - Muenzen, Colette

AU - Neuringer, Isabel

AU - Racln, Mary

AU - Rosenberg, Judlth

AU - Silva, Holly

AU - Williams, Paula

PY - 1985

Y1 - 1985

N2 - Anhydride acylation reactions of a variety of substituted arylhydrazines under mild conditions led to controlled formation of the acid phenylhydrazides I (Table I). The procedures were tailored to the particular state of the starting arylhydrazine. Second-stage acylation of phenylhydrazides conveniently produced the N,N'-diacylphenylhydrazines II (Table II), In which the acyl groups were the same or nonidentical. β acylation of phenylhydrazine resulted In significant changes In the ultraviolet spectrum (Table III); the ultraviolet spectra thus provide useful data in the determination of the extent and site of acylation.

AB - Anhydride acylation reactions of a variety of substituted arylhydrazines under mild conditions led to controlled formation of the acid phenylhydrazides I (Table I). The procedures were tailored to the particular state of the starting arylhydrazine. Second-stage acylation of phenylhydrazides conveniently produced the N,N'-diacylphenylhydrazines II (Table II), In which the acyl groups were the same or nonidentical. β acylation of phenylhydrazine resulted In significant changes In the ultraviolet spectrum (Table III); the ultraviolet spectra thus provide useful data in the determination of the extent and site of acylation.

UR - http://www.scopus.com/inward/record.url?scp=0006626991&partnerID=8YFLogxK

U2 - 10.1021/je00039a036

DO - 10.1021/je00039a036

M3 - Article

AN - SCOPUS:0006626991

SN - 0021-9568

VL - 30

SP - 129

EP - 131

JO - Journal of Chemical and Engineering Data

JF - Journal of Chemical and Engineering Data

IS - 1

ER -

Acylation Reactions of Phenylhydrazines. Preparation and Properties of New Diacylphenylhydrazines

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