A tris(μ-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue

Liviu M. Mirica; T. Daniel P. Stack

doi:10.1021/ic048182b

A tris(μ-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue

Liviu M. Mirica
, T. Daniel P. Stack

Research output: Contribution to journal › Article › peer-review

79 Scopus citations

Abstract

The reaction of a copper(I) complex with a sterically demanding secondary diamine ligand and O₂ yields a tris(μ-hydroxy)tricopper-(II) complex. This complex is a structural model of the proposed native intermediate in multicopper oxidases, with interesting structural, magnetic, and solution properties.

Original language	English
Pages (from-to)	2131-2133
Number of pages	3
Journal	Inorganic Chemistry
Volume	44
Issue number	7
DOIs	https://doi.org/10.1021/ic048182b
State	Published - Apr 7 2005

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title = "A tris(μ-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue",

abstract = "The reaction of a copper(I) complex with a sterically demanding secondary diamine ligand and O2 yields a tris(μ-hydroxy)tricopper-(II) complex. This complex is a structural model of the proposed native intermediate in multicopper oxidases, with interesting structural, magnetic, and solution properties.",

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AU - Mirica, Liviu M.

AU - Stack, T. Daniel P.

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N2 - The reaction of a copper(I) complex with a sterically demanding secondary diamine ligand and O2 yields a tris(μ-hydroxy)tricopper-(II) complex. This complex is a structural model of the proposed native intermediate in multicopper oxidases, with interesting structural, magnetic, and solution properties.

AB - The reaction of a copper(I) complex with a sterically demanding secondary diamine ligand and O2 yields a tris(μ-hydroxy)tricopper-(II) complex. This complex is a structural model of the proposed native intermediate in multicopper oxidases, with interesting structural, magnetic, and solution properties.

UR - https://www.scopus.com/pages/publications/16244375222

U2 - 10.1021/ic048182b

DO - 10.1021/ic048182b

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

A tris(μ-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue

Abstract

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