A study of the metastable dissociations of formate esters: A McLafferty rearrangement to a distonic radical cation

Keyphrases

• Dissociation 100%
• Radical Cation 100%
• McLafferty Rearrangement 100%
• Distonic Radical Cations 100%
• Formate Esters 100%
• Fragment Ions 66%
• Propyl 66%
• Formate 66%
• Distonic 66%
• Tandem Mass Spectrometry 33%
• Molecular Ions 33%
• Appearance Energy 33%
• Propylene 33%
• Activation Energy 33%
• Unimolecular Dissociation 33%
• Internal Energy 33%
• Ionization Energy 33%
• Ion Kinetic Energy 33%
• Unimolecular Fragmentation 33%
• Kinetic Energy Release 33%
• Hydrogen Atom Transfer 33%
• Time-of-flight Mass Spectrum 33%
• Alkyl Formate 33%
• Threshold Photoelectron-photoion Coincidence 33%
• Butyl Formate 33%
• Heat of Formation 33%

Chemistry

• Radical Cation 100%
• McLafferty Rearrangement 100%
• Formate Ester 100%
• Kinetic Energy 50%
• Formate 50%
• Tandem Mass Spectrometry 25%
• Molecular Ion 25%
• Hydrogen Atom 25%
• Reaction Activation Energy 25%
• Enthalpy of Formation 25%
• Ionization Potential 25%
• Internal Energy 25%
• Butyl Formate 25%
• Photoelectron-Photoion Coincidence 25%
• formation 25%