TY - JOUR
T1 - A Study of C5H10 radical cations by collisionally activated dissociation, charge stripping, and low energy ion‐molecule reactions
AU - Miller, D. L.
AU - Gross, M. L.
PY - 1983/6
Y1 - 1983/6
N2 - C5H10 radical cations generated from a variety of olefins and cycloalkanes were investigated by collisionally activated dissociation, charge stripping, and low energy ion‐molecule reactions. It has been determined that all of the isomers studied can be distinguished by charge stripping, whereas collisionally activated dissociation and the ion‐molecule reactions are less informative. The radical cations from cyclopentane, methylcyclobutane and substituted cyclopropanes retain their cyclic structures for at least a fraction of the population having lifetimes in the microsecond range.
AB - C5H10 radical cations generated from a variety of olefins and cycloalkanes were investigated by collisionally activated dissociation, charge stripping, and low energy ion‐molecule reactions. It has been determined that all of the isomers studied can be distinguished by charge stripping, whereas collisionally activated dissociation and the ion‐molecule reactions are less informative. The radical cations from cyclopentane, methylcyclobutane and substituted cyclopropanes retain their cyclic structures for at least a fraction of the population having lifetimes in the microsecond range.
UR - http://www.scopus.com/inward/record.url?scp=84989060095&partnerID=8YFLogxK
U2 - 10.1002/oms.1210180604
DO - 10.1002/oms.1210180604
M3 - Article
AN - SCOPUS:84989060095
SN - 0030-493X
VL - 18
SP - 239
EP - 244
JO - Organic Mass Spectrometry
JF - Organic Mass Spectrometry
IS - 6
ER -