A polymeric pseudorotaxane constructed from cucurbituril and aniline, and stabilization of its radical cation

Yu Liu; Jun Shi; Yong Chen; Chen Feng Ke

doi:10.1002/anie.200802805

A polymeric pseudorotaxane constructed from cucurbituril and aniline, and stabilization of its radical cation

Yu Liu
, Jun Shi
, Yong Chen
, Chen Feng Ke

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

95 Scopus citations

Abstract

(Chemical Equation Presented) Picking up the thread: A polypseudorotaxane 1 with a regular one-dimensional linear structure has been constructed in satisfactory yield from cucurbit[7]uril and polyaniline (PANI). The complexation with cucurbituril not only enhances the water solubility of the PANI (see picture; after 10 h), but also effectively stabilizes its radical cation form, that is, the conductive doped form, as shown by EPR spectroscopy.

Original language	English
Pages (from-to)	7293-7296
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	38
DOIs	https://doi.org/10.1002/anie.200802805
State	Published - Sep 8 2008

Keywords

Cucurbiturils
Inclusion compounds
Rotaxanes
Self-assembly
Supramolecular chemistry

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10.1002/anie.200802805

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abstract = "(Chemical Equation Presented) Picking up the thread: A polypseudorotaxane 1 with a regular one-dimensional linear structure has been constructed in satisfactory yield from cucurbit[7]uril and polyaniline (PANI). The complexation with cucurbituril not only enhances the water solubility of the PANI (see picture; after 10 h), but also effectively stabilizes its radical cation form, that is, the conductive doped form, as shown by EPR spectroscopy.",

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AU - Liu, Yu

AU - Shi, Jun

AU - Chen, Yong

AU - Ke, Chen Feng

PY - 2008/9/8

Y1 - 2008/9/8

N2 - (Chemical Equation Presented) Picking up the thread: A polypseudorotaxane 1 with a regular one-dimensional linear structure has been constructed in satisfactory yield from cucurbit[7]uril and polyaniline (PANI). The complexation with cucurbituril not only enhances the water solubility of the PANI (see picture; after 10 h), but also effectively stabilizes its radical cation form, that is, the conductive doped form, as shown by EPR spectroscopy.

AB - (Chemical Equation Presented) Picking up the thread: A polypseudorotaxane 1 with a regular one-dimensional linear structure has been constructed in satisfactory yield from cucurbit[7]uril and polyaniline (PANI). The complexation with cucurbituril not only enhances the water solubility of the PANI (see picture; after 10 h), but also effectively stabilizes its radical cation form, that is, the conductive doped form, as shown by EPR spectroscopy.

KW - Cucurbiturils

KW - Inclusion compounds

KW - Rotaxanes

KW - Self-assembly

KW - Supramolecular chemistry

UR - https://www.scopus.com/pages/publications/53249138298

U2 - 10.1002/anie.200802805

DO - 10.1002/anie.200802805

M3 - Article

AN - SCOPUS:53249138298

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 38

ER -

A polymeric pseudorotaxane constructed from cucurbituril and aniline, and stabilization of its radical cation

Abstract

Keywords

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