A five-coordinate Ni(i) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane

Leonel Griego; Toby J. Woods; Liviu M. Mirica

doi:10.1039/d2cc02516g

A five-coordinate Ni(i) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane

Leonel Griego, Toby J. Woods, Liviu M. Mirica

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7 Scopus citations

Abstract

An isolated Ni(ii)-nitrosyl complex supported by the bulky tridentate 1,4,7-triisopropyl-1,4,7-triazacyclononane (iPr₃TACN) ligand was obtained from the reaction of a Ni(ii) dimethyl complex with NOPF₆, suggesting the in situ formation of a Ni(i) species that reacts with the resulting NO product. Use of a π-acceptor ancillary isocyanide ligand led to the isolation and characterization of an uncommon 5-coordinate Ni(i) complex supported by the iPr₃TACN ligand and tert-butylisocyanide.

Original language	English
Pages (from-to)	7360-7363
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	53
DOIs	https://doi.org/10.1039/d2cc02516g
State	Published - Jun 14 2022

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title = "A five-coordinate Ni(i) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane",

abstract = "An isolated Ni(ii)-nitrosyl complex supported by the bulky tridentate 1,4,7-triisopropyl-1,4,7-triazacyclononane (iPr3TACN) ligand was obtained from the reaction of a Ni(ii) dimethyl complex with NOPF6, suggesting the in situ formation of a Ni(i) species that reacts with the resulting NO product. Use of a π-acceptor ancillary isocyanide ligand led to the isolation and characterization of an uncommon 5-coordinate Ni(i) complex supported by the iPr3TACN ligand and tert-butylisocyanide.",

author = "Leonel Griego and Woods, {Toby J.} and Mirica, {Liviu M.}",

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T1 - A five-coordinate Ni(i) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane

AU - Griego, Leonel

AU - Woods, Toby J.

AU - Mirica, Liviu M.

PY - 2022/6/14

Y1 - 2022/6/14

N2 - An isolated Ni(ii)-nitrosyl complex supported by the bulky tridentate 1,4,7-triisopropyl-1,4,7-triazacyclononane (iPr3TACN) ligand was obtained from the reaction of a Ni(ii) dimethyl complex with NOPF6, suggesting the in situ formation of a Ni(i) species that reacts with the resulting NO product. Use of a π-acceptor ancillary isocyanide ligand led to the isolation and characterization of an uncommon 5-coordinate Ni(i) complex supported by the iPr3TACN ligand and tert-butylisocyanide.

AB - An isolated Ni(ii)-nitrosyl complex supported by the bulky tridentate 1,4,7-triisopropyl-1,4,7-triazacyclononane (iPr3TACN) ligand was obtained from the reaction of a Ni(ii) dimethyl complex with NOPF6, suggesting the in situ formation of a Ni(i) species that reacts with the resulting NO product. Use of a π-acceptor ancillary isocyanide ligand led to the isolation and characterization of an uncommon 5-coordinate Ni(i) complex supported by the iPr3TACN ligand and tert-butylisocyanide.

UR - http://www.scopus.com/inward/record.url?scp=85132766789&partnerID=8YFLogxK

U2 - 10.1039/d2cc02516g

DO - 10.1039/d2cc02516g

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AN - SCOPUS:85132766789

SN - 1359-7345

VL - 58

SP - 7360

EP - 7363

JO - Chemical Communications

JF - Chemical Communications

IS - 53

ER -

A five-coordinate Ni(i) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane

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