A bulky 1,4,7-triazacyclononane and acetonitrile, a Goldilocks system for probing the role of Ni^III and Ni^I centers in cross-coupling catalysis

Keyphrases

• Alkyl 100%
• Acetonitrile 100%
• 1,4,7-triazacyclononane 100%
• Cross-coupling Catalysis 100%
• Goldilocks 100%
• Ni(III) 60%
• Cross-coupling Reaction 40%
• Beneficial Effects 20%
• Well-defined 20%
• Transmetalation 20%
• Beneficial Role 20%
• Increased Yield 20%
• Nitriles 20%
• Reductive Elimination 20%
• Ni(II) Complex 20%
• Ni-catalyzed 20%
• Oxidative Addition 20%
• Kumada Coupling 20%
• Efficient Catalyst 20%
• Nickel-catalyzed Cross-coupling 20%
• Organometallic Species 20%
• N-donor Ligands 20%
• Alkyl Nitriles 20%
• Coordinating Solvents 20%
• Addition-elimination 20%
• Bulky Ligands 20%

Chemistry

• Acetonitrile 100%
• Metallocene 100%
• Cross-Coupling Reaction 66%
• Nitrile 66%
• Transmetalation 33%
• Reductive Elimination Reaction 33%
• Oxidative Addition 33%
• Kumada Cross-Coupling 33%
• N-Donor Ligand 33%